Nickel phosphide nanocatalysts for the chemoselective hydrogenation of alkynes
نویسندگان
چکیده
منابع مشابه
Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol
Few methods permit the hydrogenation of alkenes to a thermodynamically favored configuration when steric effects dictate the alternative trajectory of hydrogen delivery. Dissolving metal reduction achieves this control, but with extremely low functional group tolerance. Here we demonstrate a catalytic hydrogenation of alkenes that affords the thermodynamic alkane products with remarkably broad ...
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Reduction of aldehydes to the corresponding alcohols is one of the most fundamental and useful reactions that are important in the pharmaceutical and chemical industry. Among the various available reduction protocols for the synthesis of valuable hydroxy compounds, catalytic transfer hydrogenation (TH) has emerged as the most viable, mainly due to the non-involvement of highly flammable and exp...
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ژورنال
عنوان ژورنال: Nano Today
سال: 2012
ISSN: 1748-0132
DOI: 10.1016/j.nantod.2011.12.003